Aqueous-phase oxidation of alcohols with green oxidants (Oxone and hydrogen peroxide) in the presence of MgFe2O4 magnetic nanoparticles as an efficient and reusable catalyst
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Abstract:
Nanomagnetic MgFe2O4 is an active, stable, and reusable catalyst for the oxidation of alcohols. The oxidation of various primary and secondary alcohols has been examined and related corresponding products were obtained in good yields. The reactions were carried out in the presence of water as solvent and oxone (at room temperature) or H2O2 (at 60 ºC) as an oxidant. The catalyst was investigated by X-ray powder diffraction, scanning electron microscope, inductively coupled plasma and infrared techniques. Furthermore, the catalyst could be easily recovered and reused up to 7 runs without loss of activity.
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aqueous-phase oxidation of alcohols with green oxidants (oxone and hydrogen peroxide) in the presence of mgfe2o4 magnetic nanoparticles as an efficient and reusable catalyst
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چکیده ندارد.
magnetic znfe2o4 nanoparticles as an efficient catalyst for the oxidation of alcohols to carbonyl compounds in the presence of oxone as an oxidant
zinc ferrite (znfe2o4) nanoparticles were synthesized via the auto-combustion assisted sol-gel method of zn2+ and fe3+ ions (molar ratio 1:2) in ammonia solution. the prepared nanomagnetic catalyst was characterized by ir, xrd, sem and icp. the diameter of the znfe2o4 mnps (63.7 nm) was determined by debye-scherre equation via their xrd pattern. nanomagnetic znfe2o4 efficiently catalyzes oxidat...
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Journal title
volume 6 issue 4
pages 264- 272
publication date 2016-10-01
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